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(E)-Ethyl 4-(diethoxyphosphoryl)but-2-enoate

CAS 42516-28-9 C10H19O5P 250.23 g/mol Catalogue item Acids, Esters & Lactones
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Structure of (E)-Ethyl 4-(diethoxyphosphoryl)but-2-enoate, CAS 42516-28-9
Structure · C10H19O5P
CAS number
42516-28-9
Molecular formula
C10H19O5P
Molecular weight
250.23 g/mol
Standard packing
1kg / 25kg / 100kg

CAS 42516-28-9, (E)-Ethyl 4-(diethoxyphosphoryl)but-2-enoate, is a C10H19O5P ester – the protected form of the corresponding acid.

Methyl and ethyl esters of this size also serve as enolate equivalents in Claisen and alkylation chemistry, where the ester stabilises the carbanion. Because the configuration is specified, the useful comparison is with the other isomer of the same skeleton rather than with another chain length. The acetal is a masked carbonyl. It survives base and hydride conditions and is opened under acid, which is what makes it useful in the middle of a sequence.

The formula C10H19O5P resolves to 10 carbons with 5 oxygens and one phosphorus. At 10 carbons the entry is an oil or a low-melting solid, and it is handled at ambient temperature in most steps.

Handling and storage

Store neutral, dry and closed. The free acid that appears on hydrolysis is the impurity to check on a lot that has been open for months.

Ordering

Standard packing 1kg / 25kg / 100kg. Other unit weights are quoted per lot and confirmed in writing before the material is packed. Release testing covers identity and assay; the impurity profile is available on request rather than being printed on this page.

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Entry(E)-Ethyl 4-(diethoxyphosphoryl)but-2-enoate
CAS42516-28-9
Typical lead timeStock or 2–4 weeks
DocumentationCOA, SDS, spec sheet

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(E)-Ethyl 4-(diethoxyphosphoryl)but-2-enoate (42516-28-9)

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