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Protected & Silylated Alkynes

Alkynes carrying a protecting group: a trimethylsilyl or triethylsilyl cap on the alkyne carbon, or a tetrahydropyranyl ether on an adjacent hydroxyl. These entries exist for the middle of a sequence, where the group underneath has to survive steps that would otherwise attack it. The protecting group is removed under conditions that leave the rest of the molecule alone – fluoride for the silyl cap, mild acid for the THP ether.

3 catalogue entries group protected-alkynes Typical use: TMS / THP cleavage ยท Grignard
CASCompoundFormulaMWPackingQuote
18180-30-82-((prop-2-yn-1-yloxy)Methyl)oxiraneC6H8O2112.131kg / 25kg / 100kgRequest
6089-04-92-Propynyl 2-pyranyl etherC8H12O2140.181kg / 25kg / 100kgRequest
1066-54-2TrimethylsilylacetyleneC5H10Si98.221kg / 25kg / 100kgRequest
Entries are listed alphabetically. Packing is the standard unit weight; other quantities are quoted per lot.
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Protected & Silylated Alkynes outside the catalogue

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Group: Protected & Silylated Alkynes

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